Inelastic neutron scattering investigation of hydrating tricalcium and dicalcium silicate mixture pastes: Ca(OH)2 formation and evolution of strength

نویسندگان

  • Vanessa K. Peterson
  • Dan A. Neumann
  • Richard A. Livingston
چکیده

The hydration of controlled tricalcium and dicalcium silicate mixtures was investigated using inelastic neutron scattering. The amount of Ca(OH)2 produced by each mixture was quantified based on the vibrational mode at approximately 41 meV. The results of compressive strength testing correlate with the amount of Ca(OH)2 produced and with previous results from quasielastic neutron scattering. These results establish a link between hydration mechanics and the evolution of hydration products leading to desirable properties, such as strength.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Hydration of cement: The application of quasielastic and inelastic neutron scattering

Quasielastic and inelastic neutron scattering have been highlighted as excellent tools for studying the hydration of cement components. Here, the complimentary application of inelastic and time-resolved quasielastic neutron scattering to investigate the reaction kinetics during the crucial first 24 h of hydration will be highlighted. Some recent results include the interaction of tricalcium and...

متن کامل

State of Water in Hydrating Tricalcium Silicate and Portland Cement Pastes as Measured by Quasi-Elastic Neutron Scattering

Quasi-elastic neutron scattering (QENS) was used to monitor the state of water in portland cement and tricalcium silicate pastes during the first 2 days of hydration at three different temperatures. By applying a double-Lorentzian rather than a single-Lorentzian fitting function, the QENS signal from water at a given hydration time was divided into three separate populations arising from liquid...

متن کامل

Quasielastic and inelastic neutron scattering study of the hydration of monoclinic and triclinic tricalcium silicate

The hydration of Mg-stabilized triclinic and monoclinic tricalcium silicate samples were studied using quasielastic neutron scattering to follow the fixation of hydrogen into the reaction products and by applying hydration models to the data. The quantity of Ca(OH)2 produced during hydration was also determined using inelastic neutron scattering. The monoclinic form was found to be intrinsicall...

متن کامل

CALCIUM PHOSPHATE CEMENT: STUDY OF (BETA-TRICALCIUM PHOSPHATE, DICALCIUM PHOSPHATE AND CALCIUM CARBONATE SYSTEM

Calcium phosphate cements (CPCs), using B-tricalcium phosphate (ß-TCP, Ca3 (P04)2), dicalcium phosphate (DCP, CaHP04), calcium carbonate (Ca CO3), and hydroxylapatite (HAp, Ca10(P04)6(OH)2) as powder cement and disodium hydrogen phosphate (Na2HP04) solution as liquid component were prepared. After mixing the powder and liquid constituents, injectable and self-setting calcium phosphate cements (...

متن کامل

Structural studies on hydrating cement pastes

The development of the mesoscopic material structure during the hydration of ordinary Portland cement paste is studied by small-angle neutron scattering. Results on the time dependence of radii of gyration (Guinier region) and exponents (Porod region) are given and discussed. Introduction Building materials like hardened cement are heterogeneous. Their useful properties (as strength, porosity, ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2006